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二异丙基二硫代氨基甲酸钼配合物的室温固相合成、表征及晶体结构 预览 被引量:3

Solid Phase Synthesis at Room Temperature,Characterization and Crystal Structure of bis(diiso-propylcarbamodithioato-S,S’) Molybdenum
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摘要 磷钼酸与二异丙基二硫代氨基甲酸钠通过室温固相反应,合成了二异丙基二硫代氨基甲酸合钼,用红外光谱、X-射线粉末衍射谱和TG—DTA,对产物进行了表征,并且测定其单晶结构。标题化合物属单斜晶系,P21/c空间群,晶胞参数α=0.81570(16)nm,b=1.7844(4)nm,C=1.5648(5)nm,β=110.38(3)°,V=2.1351(9)nm^3,Z=4,Dc=1.396Mg/m^3,F(000)=928,μ=1.002mm^-1,R=0.0888,Rw=0.1442,GOF=1.092。 Bis(diiso-propylcarbamodithioato-S,S’) Molybdenum was synthesized by the solid phase reaction of phosphomolybdic acid and diiso-propylcarbamodithioato sodium at room temperature. The product was characterized by IR, X-ray powder diffraction and TG-DTA. Its single crystal was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with a space group P2 1/c,a=0.815 70(16)nm,b=1.784 4(4)nm,c=1.564 8(5)nm,β=110.38(3)°, V= 2.135 1(9) nm 3,Z=4,D c =1.396 Mg/m 3,F(000)=928, μ=1.002 mm -1 ,R=0.088 8,R w =0.144 2,GOF=1.092.
作者 马建旗 卑凤利 李俊琦 杨绪杰 陆路德 汪信 MA Jian-qi,BEI Feng-li,LI Jun-qi,YANG Xu-jie, LU Lu-de,WANG Xin (Materials Chemistry Laboratory, NUST, Nanjing 210094,China)
出处 《南京理工大学学报:自然科学版》 CAS CSCD 北大核心 2004年第6期 648-652,共5页 Journal of Nanjing University of Science and Technology(Nature Science)
基金 国家自然科学基金 (5 0 372 0 2 8)
关键词 二异丙基二硫代氨基甲酸钼 室温固相反应 晶体结构 bis(diiso-propylcarbamodithioato-S,S’) Molybdenum solid phase reaction at room temperature crystal structure
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