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缩氨基硫脲类化合物的应用及展望 预览 被引量:6

Prospects and applications of thiosemicarbazones in spectrophotometry
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摘要 缩氨基硫脲类Schiff碱化合物是一类十分有效的分析试剂.评述了近年来缩氨基硫脲化合物在普通光忖度法、萃取光度法、动力学光度法、荧光光度法、流动注射光度法及原子吸收光度法等光度分析中的应用研究情况,并就该类显色剂显色反应的光谱特性、分析性能及其应用等方面的情况作了分析,指出了应用超分子化学原理,并进一步研究其结构与性能的关系,从分子水平上开发该类功能分子的性能,不仅有助于设计性能更好的分析试剂,而且会拓展其应用领域. Thiosemicarbazones are a class of schiff base acting as effective chelating agents. This paper presented applications of thiosemicarbazones in direct spectrophotometric method,extractive spectrophotometric method,kinetic photometric method,fluorometric method,flow injection spectrophotometric method and atomic absorption spectrophotometry. The related research and development were reviewed,such as spectral properties,analytical performances,applications and so on. It can be concluded that,after application the supramolecular chemistry principle to researching the relation between their properties and structures and to developing the performances of these functional molecules at the molecular level,not only the analytical reagents with better property can be well designed,but also the application scope can be broadened.
作者 张霞 刘万毅 张境 ZHANG Xia,LIU Wan yi*,ZHANG Jing (College of Chemisty and Chemical Engineering / Key Laboratory of Energy Resources &Chemical; Engineering, Ningxia University,Yinchuan 750021,China)
机构地区 宁夏大学
出处 《宁夏工程技术》 CAS 2005年第1期 78-85,共8页 Ningxia Engineering Technology
基金 教育部重点研究项目,宁夏自然科学基金,宁夏大学校科研和教改项目
关键词 缩氨基硫脲 SCHIFF碱 光度分析 thiosemicarbazones schiff-base spectrophotometry
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  • 1SINGH R B, GARG B S, SINGH R P. Analytical applications of thiosemicarbazones and semicarbazones:a review[J]. Talanta, 1978, 25(11 - 12): 619. 被引量:1
  • 2SALINAS F, JIMENEZ SANCHEZ J C, GALEANO DIAZ T. Spectrophotometric determination of iron in wines, foods, and minerals with 5,5-dimethyl-1,2,3-cyclohex-anetrione 1,2-dioxime 3-thiosemicarbazone [J]. Analytical Chemistry, 1986,58 (4): 824. 被引量:1
  • 3PRAKASH K M M S, PRABHAKAR L D, Reddy D VANKATA. Rapid extraction spectrophotometric determination of platinum using anisaldehyde-4-phenyl-3-thiosemicarbazone as a chromogenic reagent[J]. Analytical Letters, 1987, 20(7): 959. 被引量:1
  • 4CALLEJON MOCHON M, MUNOZ LEYVA J A. Spectrophotometric determination of periodate with the bisthiosemicarbazones of phthalimide and 1,3-indandione[J].Microchemical Journal, 1986, 34(1): 83. 被引量:1
  • 5SHETTY P, SHETTY A N, GADAG R V. Spectroph otometric determination of palladium(Ⅱ) using piperonal thiosemicarbazone[J]. Indian Journal of Chemical Technology, 2003,10(3) :287. 被引量:1
  • 6SHETTY P, SHETTY A N, GADAG R V. Rapid spectrophotometric determination of platinum(Ⅳ) using piperonal thiosemicarbazone[J]. Indian Journal of Chemistry,2002,41A(5): 988. 被引量:1
  • 7党元林,包晓玉,卓立宏,郭应臣.D—(+)—葡萄糖缩氨基硫脲与铜的显色反应及其应用[J].分析化学,2003,31(2):253-253. 被引量:5
  • 8SALIM R, LAILA A H, QAMHIEH A. 5,5-Dimethyl1,2,3-cyclohexanetrione 1,2-dioxime 3-thiosemicarbazone as a reagent for the spectrophotometric determination of nickel and copper[J]. Spectroscopy Letters, 1988, 21(7): 541. 被引量:1
  • 9REDDY K H, PRASAD N B L. Spectrophotometric determination of copper(Ⅱ) in edible oils and seeds using novel oxime-thiosemicarbazones[J]. Indian Journal of Chemistry, 2004,43A ( 1 ): 111. 被引量:1
  • 10REDDY K H, PRASAD N B L, REDDYeddy T S.Analytical properties of 1-phenyl-1,2-propanedione-2-oxime thiosemicarbazone:simultaneous spectrophotometric determination of copper ( Ⅱ ) and nickel ( Ⅱ ) in edible oils and seeds[J]. Talanta, 2003, 59(3): 425. 被引量:1

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