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开链冠醚2,6—二(8‘—喹啉氧甲基)—4—甲基—苯甲醚及其Ag(I),Cu(Ⅱ),Ni(Ⅱ)配合物的合成与性质研究 被引量:4

Synthesis and Characterization of 2,6-Di (8’-quinolinoxy methyl)-4-methyl-anisole and Its Complexes with Silver (Ⅰ), Copper (Ⅱ) and Nickle (Ⅱ)
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摘要 设计合成一种尚未见文献报道的酚型双臂开链冠醚化合物L(L-2,6-二(8'-喹啉氧甲基)-4-甲基-苯甲醚),经元素分析,IR,^1HNMR,MS等方法确定了其组合和结构,其Ag(I),Cu(II),Ni(II)固体配合物的元素分析结果青明,金属离子不同,则其配合物的配位比(M:L)不同,Ag(I)配合物为1:1,Cu(II,Ni(II)配合物为2:3,并运用热重-差热分析对其热稳定性进行初步研究。 A novel open chain crown ether 2,6 di (8' quinolinoxy methyl) 4 methyl anisole was synthesized and characterized by elemental analysis, IR, 1HNMR and MS. Its complexes with Ag(Ⅰ), Cu(Ⅱ) and Ni(Ⅱ) were synthesized. The elemental analysis shows that with different metal ions, the ratio of metal to ligand is different. The M:L of Ag(Ⅰ) complex is 1:1, while Cu(Ⅱ) and Ni(Ⅱ) is 2:3. The complexes were also examined by thermal analysis.
作者 张前前 季振平 Zhang Qianqian1 Ji Zhenping2 Xiao Wenjin 2 Wu Chengtai 2 (1 College of Chemistry and Chemical Engineering, Ocean University of Qingdao, Qingdao, 266003) (2 College of Chemistry and Environment Science, Wuhan University, Wuhan, 430072)
出处 《青岛海洋大学学报:自然科学版》 CSCD 北大核心 2001年第3期 420-424,共5页 Journal of Ocean University of Qingdao
关键词 开链冠醚 过渡金属配合物 配位化学 配位作用 差热-热重分析 open chain crown ether transition metal complex synthesis and characterization
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