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含羟基西佛碱型大环冠醚铜(Ⅱ)、锌(Ⅱ)配合物的合成与表征 被引量:2

Studies on Synthesis of Hydroxy-Bearing Schiff Base Macrocyclic Complexes of Cu(Ⅱ) and Zn(Ⅱ)
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摘要 利用模板法合成1种新的含醇羟基西佛碱型大环冠醚L (7,11-二氮杂-3,15-二氧杂-4,5; 8,10; 13,14-三苯并环十六-6,11-二烯 -1-醇)的铜、锌配合物.经元素分析, IR、MS分析确定配合物的组成M(L2)(NO3)2 及其配位情况,由模板反应得到[1+1]型西佛碱大环化合物.DMF溶液中的电导数据证实它们均属非电离型,并运用TG-DTA分析比较铜、锌配合物的热稳定性. Copper and zinc complexes with macrocyclic Schiff base containing alcohol hydroxyl were synthesized by reaction of 1,3 bis(2 formylphenoxy) 2 propanol with m phenylenediamine by template method. The complexes were characterized by elemental analysis, IR, molar conductance and MS. Their thermal behavior was examined by DTA TG analysis.
作者 张前前 季振平 萧文锦 吴成泰 Zhang Qianqian 1 Ji Zhenping 2 Xiao Wenjin 2 Wu Chengtai 2 (1 College of Chemistry and Chemical Engineering, Ocean University of Qingdao, Qingdao 266003, China)(2 College of Chemistry and Molecule Science, Wuhan University, Wuhan 430072, China)
出处 《青岛海洋大学学报:自然科学版》 CSCD 北大核心 2002年第2期 301-304,共4页 Journal of Ocean University of Qingdao
基金 湖北省自然科学基金
关键词 西佛碱配合物 1 3-双(2-甲酰基苯氧)-2-丙醇 铜配合物 锌配合物 模板合成 抗肿瘤 医药活性 macrocyclic Schiff base 1,3 bis(2 formylphenoxy) 2 propanol copper complex zinc complex template synthesis
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