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Extending the operational lifetimes of all-direct electron transfer enzymatic biofuel cells by magnetically assembling and exchanging the active biocatalyst layers on stationary electrodes

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摘要 Enzymatic biofuel cells promise green power generation from a variety of natural resources, yet these systems all suffer from time-dependent degradati on effects, in particular progress! ng inactivation of enzymes, which severely limit the operati on al lifetimes of such power sources. To extend operational lifetimes, we introduce a method to magnetically exchange exhausted enzymes for fresh ones. To this end, anodic and cathodic enzymes or enzyme cascades are immobilized on carbon coated magnetic nanoparticles. Under the action of suitable magnetic field gradie nts, these nano particles are assembled on the respective stati onary electrodes, or released from the electrodes for collection and subsequent excha nge. We dem on strate this method on a fructose/oxygen con suming biofuel cell emplo ying fructose dehydroge nase and bilirubin oxidase as well as on anodic and cathodic cascades employing fructose dehydrogenase/invertase and bilirubin oxidase/catalase, respectively. The en zyme-modified nan oparticles support direct electro n transfer bioelectrocatalytic curre nts by wiring the redox active cofactors to the carbonaceous coating and from there to the electrode surfaces. The facile injection, assembly, and removal of enzyme-modified magnetic nan oparticles along with fuel solutio n provides a promisi ng approach to exte nd the operati on al lifetime of enzymatic biofuel cells without the need for exchanging entire systems including chambers and electrodes.
机构地区 Saumerstrasse
出处 《纳米研究:英文版》 SCIE EI CAS CSCD 2019年第4期767-775,共9页 Nano Research
作者简介 Address correspondence:Katharina Herkendell. kh@ethz.ch;Address correspondence:Ran Tel-Vered. teran@ethz.ch.
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