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Conductive property of Zr0.1Fe0.9V1.1Mo0.9O7 with low thermal expansion

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摘要 Low thermal expansion materials are mostly ceramics with low conductive property,which limits their applications in electronic devices.The poor conductive property of ceramic ZrV2O7 could be improved by bi-substitution of Fe and Mo for Zr and V,accompanied with low thermal expansion.Zr0.1Fe0.9V1.1Mo0.9O7 has electrical conductivity of 8.2×10^-5 S/cm and 9.41×10^4 S/cm at 291 K and 623 K,respectively.From 291 K to 413 K,thermal excitation leads to the increase of carrier concentration,which causes the rapid decrease of resistance.At 413–533 K,the conductivity is unchanged due to high scattering probability and a slowing increase of carrier concentration.The conductivity rapidly increases again from 533 K to 623 K due to the intrinsic thermal excitation.The thermal expansion coefficient of Zr0.1Fe0.9V1.1Mo0.9O7 is as low as 0.72×10^6 K^-1 at 140–700 K from the dilatometer measurement.These properties suggest that Zr0.1Fe0.9V1.1Mo0.9O7 has attractive application in electronic components.
作者 何小可 戚恒 徐启 刘献省 许磊 袁保合 Xiaoke He;Heng Qi;Qi Xu;Xiansheng Liu;Lei Xu;Baohe Yuan(不详)
出处 《中国物理B:英文版》 SCIE EI CAS CSCD 2019年第5期244-248,共5页 Chinese Physics B
基金 the National Natural Science Foundation of China (Grant Nos.11574276,51702097,and 11574083) the Program for Innovative Research Team (in Science and Technology) in University of Henan Province,China (Grant No.16IRTSTHN017) Henan Science and Technology Development Project,China (Grant No.182102210241).
作者简介 Corresponding.author:刘献省.E-mail:liuxiansheng69@126.com;Corresponding.author:袁保合.E-mail:yuanbaohe@ncwu.edu.cn.
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